Publications

2014

• Finite ballooning angle effects on ion temperature gradient driven mode in gyrokinetic flux tube simulations
  
  • Singh Rameswar
  • Brunner Stephan
  • Ganesh R.
  • Jenko F.
  Physics of Plasmas, American Institute of Physics, 2014, 21 (3), pp.032115. This paper presents effects of finite ballooning angles on linear ion temperature gradient (ITG) driven mode and associated heat and momentum flux in Gyrokinetic flux tube simulation GENE. It is found that zero ballooning angle is not always the one at which the linear growth rate is maximum. The ITG mode acquires a short wavelength (SW) branch (k⊥ρi > 1) when growth rates maximized over all ballooning angles are considered. However, the SW branch disappears on reducing temperature gradient showing characteristics of zero ballooning angle SWITG in case of extremely high temperature gradient. Associated heat flux is even with respect to ballooning angle and maximizes at nonzero ballooning angle while the parallel momentum flux is odd with respect to the ballooning angle. (10.1063/1.4868425)
  DOI : 10.1063/1.4868425
• Numerical computation of the modified plasma dispersion function with curvature
  
  • Gürcan Özgür D.
  Journal of Computational Physics, Elsevier, 2014, 269, pp.156-167. A particular generalization of the plasma dispersion function, which is linked to the regular plasma dispersion function via recurrence relations is discussed. The generalization allows a fast numerical implementation of a certain two-dimensional integral that appears in the description of the plasma dispersion in curved geometry, by reducing it to a single integral over a function involving the generalized plasma dispersion function. The local dielectric function of the toroidal ion temperature gradient driven mode can be written in terms of these integral functions. A matrix method is proposed to combine the consecutive integrals as a single 1D integral over a single integrand. The method allows two orders of magnitude speed up over the 2D integral implementation. Using various optimizations and an efficient implementation of the regular plasma dispersion function, further speed up is obtained. (C) 2014 Elsevier Inc. All rights reserved. (10.1016/j.jcp.2014.03.017)
  DOI : 10.1016/j.jcp.2014.03.017
• Momentum transport in the vicinity of q<SUB>min</SUB> in reverse shear tokamaks due to ion temperature gradient turbulence
  
  • Singh Rameswar
  • Singh R.
  • Jhang Hogun
  • Diamond P.H.
  Physics of Plasmas, American Institute of Physics, 2014, 21 (1), pp.012302. This paper presents effects of finite ballooning angles on linear ion temperature gradient (ITG) driven mode and associated heat and momentum flux in Gyrokinetic flux tube simulation GENE. It is found that zero ballooning angle is not always the one at which the linear growth rate is maximum. The ITG mode acquires a short wavelength (SW) branch (k&#8869;&#961;i&#8201;>&#8201;1) when growth rates maximized over all ballooning angles are considered. However, the SW branch disappears on reducing temperature gradient showing characteristics of zero ballooning angle SWITG in case of extremely high temperature gradient. Associated heat flux is even with respect to ballooning angle and maximizes at nonzero ballooning angle while the parallel momentum flux is odd with respect to the ballooning angle. (10.1063/1.4861625)
  DOI : 10.1063/1.4861625
• Surface deactivation of vibrationally excited N<SUB>2</SUB> studied using infrared titration combined with quantum cascade laser absorption spectroscopy
  
  • Marinov Daniil
  • Lopatik D.
  • Guaitella Olivier
  • Ionikh Y.
  • Röpcke J.
  • Rousseau Antoine
  Journal of Physics D: Applied Physics, IOP Publishing, 2014, 47 (1), pp.015203. The wall de-excitation probability of vibrationally excited nitrogen molecules was determined using infrared (IR) titration with CO, CO 2 and N 2 O. Gas mixtures of N 2 with 0.05?0.5% of CO (CO 2 or N 2 O) were excited by a pulsed dc discharge at p = 133 Pa in a cylindrical discharge tube. During the afterglow, the vibrational relaxation of titrating molecules was monitored in situ with quantum cascade laser absorption spectroscopy. The value of was deduced from measured vibrational relaxation times using a model of vibrational kinetics in N 2 . It was found that adsorption of IR tracers on the surface may increase the value of by a factor up to two, depending on the molecule and the surface material. It was demonstrated that N 2 O is the most inert and reliable tracer and it was used for the determination of on silica, Pyrex, TiO 2 , Al 2 O 3 and anodized aluminum. Pretreatment of the silica surface by low-pressure plasma was found to have a strong effect on the vibrational de-excitation. Values of measured after O 2 , Ar and N 2 plasma pretreatment of the same silica discharge tube were 5.7 × 10 ?4 , 8.2 × 10 ?4 and 11 × 10 ?4 , respectively. This study clearly demonstrates that the presence of adsorbed atoms and molecules on the surface may significantly alter the value of . (10.1088/0022-3727/47/1/015203)
  DOI : 10.1088/0022-3727/47/1/015203
• Theory for helical turbulence under fast rotation
  
  • Galtier Sébastien
  Physical Review E, American Physical Society (APS), 2014, 89, pp.41001. Recent numerical simulations have shown the strong impact of helicity on homogeneous rotating hydrodynamic turbulence. The main effect can be summarized through the law n ñ=-4, where n and ñ are the power law indices of the one-dimensional energy and helicity spectra, respectively. We investigate this rotating turbulence problem in the small Rossby number limit by using the asymptotic weak turbulence theory derived previously. We show that the empirical law is an exact solution of the helicity equation where the power law indices correspond to perpendicular (to the rotation axis) wave number spectra. It is proposed that when the cascade towards small scales tends to be dominated by the helicity flux the solution tends to ñ=-2, whereas it is ñ=-3/2 when the energy flux dominates. The latter is compatible with the solution previously observed numerically and derived theoretically in the weak turbulence regime when only the energy equation is used, whereas the former solution is constrained by a locality condition. (10.1103/PhysRevE.89.041001)
  DOI : 10.1103/PhysRevE.89.041001
• Quantified energy dissipation rates in the terrestrial bow shock: 2. Waves and dissipation
  
  • Wilson Iii L. B.
  • Sibeck David G.
  • Breneman A. W.
  • Le Contel Olivier
  • Cully C. M.
  • Turner D. L.
  • Angelopoulos V.
  • Malaspina D. M.
  Journal of Geophysical Research Space Physics, American Geophysical Union/Wiley, 2014, 119 (8), pp.6475-6495. We present the first quantified measure of the energy dissipation rates, due to wave-particle interactions, in the transition region of the Earth's collisionless bow shock using data from the Time History of Events and Macroscale Interactions during Substorms spacecraft. Our results show that wave-particle interactions can regulate the global structure and dominate the energy dissipation of collisionless shocks. In every bow shock crossing examined, we observed both low-frequency (<10 Hz) and high-frequency (&#8819;10 Hz) electromagnetic waves throughout the entire transition region and into the magnetosheath. The low-frequency waves were consistent with magnetosonic-whistler waves. The high-frequency waves were combinations of ion-acoustic waves, electron cyclotron drift instability driven waves, electrostatic solitary waves, and whistler mode waves. The high-frequency waves had the following: (1) peak amplitudes exceeding deltaB 10 nT and deltaE 300 mV/m, though more typical values were deltaB 0.1-1.0 nT and deltaE 10-50 mV/m; (2) Poynting fluxes in excess of 2000 muW m<SUP>-2</SUP> (typical values were 1-10 muW m<SUP>-2</SUP>); (3) resistivities > 9000 Omega m; and (4) associated energy dissipation rates >10 muW m<SUP>-3</SUP>. The dissipation rates due to wave-particle interactions exceeded rates necessary to explain the increase in entropy across the shock ramps for 90% of the wave burst durations. For 22% of these times, the wave-particle interactions needed to only be <= 0.1% efficient to balance the nonlinear wave steepening that produced the shock waves. These results show that wave-particle interactions have the capacity to regulate the global structure and dominate the energy dissipation of collisionless shocks. (10.1002/2014JA019930)
  DOI : 10.1002/2014JA019930
• The double well mass filter
  
  • Gueroult R
  • Fisch Nathaniel J.
  • Rax Jean-Marcel
  Physics of Plasmas, American Institute of Physics, 2014, 21 (2), pp.020701. Various mass filter concepts based on rotating plasmas have been suggested with the specific purpose of nuclear waste remediation. We report on a new rotating mass filter combining radial separation with axial extraction. The radial separation of the masses is the result of a “double-well” in effective radial potential in rotating plasma with a sheared rotation profile. (10.1063/1.4864325)
  DOI : 10.1063/1.4864325
• Investigation of drift velocity effects on the EDGE and SOL transport.
  
  • Leybros Robin
  • Bufferand H.
  • Ciraolo G.
  • Fedorczak N.
  • Ghendrih Ph.
  • Hennequin Pascale
  • Marandet Y.
  • Serre E.
  • Schwander F.
  • Tamain P.
  , 2014.
• Ambipolar and non-ambipolar diffusion in an rf plasma source containing a magnetic filter
  
  • Lafleur Trevor
  • Aanesland Ane
  Physics of Plasmas, American Institute of Physics, 2014, 21, pp.063510. By placing a magnetic filter across a rectangular plasma source (closed at one end with a ceramic plate and an rf antenna, and terminated at the opposite end by a grounded grid), we experimentally investigate the effect of conducting and insulating source walls on the nature of the plasma diffusion phenomena. The use of a magnetic filter creates a unique plasma, characterized by a high upstream electron temperature (Teu&#8764;5 eV) near the rf antenna and a low downstream electron temperature (Ted&#8764;1 eV) near the grid, which more clearly demonstrates the role of the source wall materials. For conducting walls a net ion current to ground is measured on the grid, and the plasma potential is determined by a mean electron temperature within the source. For insulating walls the plasma potential is determined by the downstream electron temperature (i.e., Vp&#8764;5.2Ted in argon), and the net current to the grid is exactly zero. Furthermore, by inserting a small additional upstream conductor (that can be made floating or grounded through an external circuit switch), we demonstrate that the plasma potential can be controlled and set to a low (Vp&#8764;5.2Ted), or high (Vp&#8764;5.2Teu) value. (10.1063/1.4885109)
  DOI : 10.1063/1.4885109
• Electron heating in capacitively coupled plasmas revisited
  
  • Lafleur Trevor
  • Chabert Pascal
  • Booth Jean-Paul
  Plasma Sources Science and Technology, IOP Publishing, 2014, 23 (3), pp.035010. We revisit the problem of electron heating in capacitively coupled plasmas (CCPs), and propose a method for quantifying the level of collisionless and collisional heating in plasma simulations. The proposed procedure, based on the electron mechanical energy conservation equation, is demonstrated with particle-in-cell simulations of a number of single and multi-frequency CCPs operated in regimes of research and industrial interest. In almost all cases tested, the total electron heating is comprised of collisional (ohmic) and pressure heating parts. This latter collisionless component is in qualitative agreement with the mechanism of electron heating predicted from the recent re-evaluation of theoretical models. Finally, in very electrically asymmetric plasmas produced in multi-frequency discharges, we observe an additional collisionless heating mechanism associated with electron inertia. (10.1088/0963-0252/23/3/035010)
  DOI : 10.1088/0963-0252/23/3/035010
• Propagation of lower-band whistler-mode waves in the outer Van Allen belt: Systematic analysis of 11 years of multi-component data from the Cluster spacecraft
  
  • Santolík O.
  • Macusova E.
  • Kolmasova Ivana
  • Cornilleau-Wehrlin Nicole
  • Conchy Y.
  Geophysical Research Letters, American Geophysical Union, 2014, 41, pp.2729-2737. Lower-band whistler-mode emissions can influence the dynamics of the outer Van Allen radiation belts. We use 11&#8201;years of measurements of the STAFF-SA instruments onboard the four Cluster spacecraft to systematically build maps of wave propagation parameters as a function of position. We determine probability distributions of wave vector angle weighted by the wave intensity. The results show that wave vector directions of intense waves are close to a Gaussian-shaped peak centered on the local magnetic field line. The width of this peak is between 10 and 20 degrees. The cumulative percentage of oblique waves is below 1015%. This result is especially significant for an important class of whistler-mode emissions of lower-band chorus at higher latitudes, well outside their source region, where a simple ray tracing model fails and another mechanism is necessary to keep the wave vectors close to the field-aligned direction. (10.1002/2014GL059815)
  DOI : 10.1002/2014GL059815
• Electron energy distributions in a magnetized inductively coupled plasma
  
  • Song Sang-Heon
  • Yang Yang
  • Chabert Pascal
  • Kushner M.J.
  Physics of Plasmas, American Institute of Physics, 2014, 21 (9), pp.093512. Optimizing and controlling electron energy distributions (EEDs) is a continuing goal in plasma materials processing as EEDs determine the rate coefficients for electron impact processes. There are many strategies to customize EEDs in low pressure inductively coupled plasmas (ICPs), for example, pulsing and choice of frequency, to produce the desired plasma properties. Recent experiments have shown that EEDs in low pressure ICPs can be manipulated through the use of static magnetic fields of sufficient magnitudes to magnetize the electrons and confine them to the electromagnetic skin depth. The EED is then a function of the local magnetic field as opposed to having non-local properties in the absence of the magnetic field. In this paper, EEDs in a magnetized inductively coupled plasma (mICP) sustained in Ar are discussed with results from a two-dimensional plasma hydrodynamics model. Results are compared with experimental measurements. We found that the character of the EED transitions from non-local to local with application of the static magnetic field. The reduction in cross-field mobility increases local electron heating in the skin depth and decreases the transport of these hot electrons to larger radii. The tail of the EED is therefore enhanced in the skin depth and depressed at large radii. Plasmas densities are non-monotonic with increasing pressure with the external magnetic field due to transitions between local and non-local kinetics. (10.1063/1.4896711)
  DOI : 10.1063/1.4896711
• Les débris spatiaux : le revers de l'ère spatiale
  
  • Aanesland Ane
  • Grondein Pascaline
  Flash X - La revue scientifique de l'Ecole polytechnique, Ecole polytechnique, 2014 (16), pp.12.
• E x B shear pattern formation by radial propagation of heat flux waves
  
  • Kosuga Y.
  • Diamond P.H.
  • Dif-Pradalier Guilhem
  • Gürcan Özgür D.
  Physics of Plasmas, American Institute of Physics, 2014, 21 (5). A novel theory to describe the formation of E x B flow patterns by radially propagating heat flux waves is presented. A model for heat avalanche dynamics is extended to include a finite delay time between the instantaneous heat flux and the mean flux, based on an analogy between heat avalanche dynamics and traffic flow dynamics. The response time introduced here is an analogue of the drivers' response time in traffic dynamics. The microscopic foundation for the time delay is the time for mixing of the phase space density. The inclusion of the finite response time changes the model equation for avalanche dynamics from Burgers equation to a nonlinear telegraph equation. Based on the telegraph equation, the formation of heat flux jams is predicted. The growth rate and typical interval of jams are calculated. The connection of the jam interval to the typical step size of the E x B staircase is discussed. (C) 2014 AIP Publishing LLC. (10.1063/1.4872018)
  DOI : 10.1063/1.4872018
• Quantified energy dissipation rates in the terrestrial bow shock: 1. Analysis techniques and methodology
  
  • Wilson Iii L. B.
  • Sibeck David G.
  • Breneman A. W.
  • Le Contel Olivier
  • Cully C. M.
  • Turner D. L.
  • Angelopoulos V.
  • Malaspina D. M.
  Journal of Geophysical Research Space Physics, American Geophysical Union/Wiley, 2014, 119 (8), pp.6455-6474. We present a detailed outline and discussion of the analysis techniques used to compare the relevance of different energy dissipation mechanisms at collisionless shock waves. We show that the low-frequency, quasi-static fields contribute less to ohmic energy dissipation, (-j·E), than their high-frequency counterparts. In fact, we found that high-frequency, large-amplitude (>100 mV/m and/or >1 nT) waves are ubiquitous in the transition region of collisionless shocks. We quantitatively show that their fields, through wave-particle interactions, cause enough energy dissipation to regulate the global structure of collisionless shocks. The purpose of this paper, part one of two, is to outline and describe in detail the background, analysis techniques, and theoretical motivation for our new results presented in the companion paper. The companion paper presents the results of our quantitative energy dissipation rate estimates and discusses the implications. Together, the two manuscripts present the first study quantifying the contribution that high-frequency waves provide, through wave-particle interactions, to the total energy dissipation budget of collisionless shock waves. (10.1002/2014JA019929)
  DOI : 10.1002/2014JA019929
• Observational evidence of electron pitch angle scattering driven by ECH waves
  
  • Kurita S.
  • Miyoshi Y.
  • Cully C. M.
  • Angelopoulos V.
  • Le Contel Olivier
  • Hikishima M.
  • Misawa H.
  Geophysical Research Letters, American Geophysical Union, 2014. Using the plasma wave and electron data obtained from Time History of Events and Macroscale Interactions during Substorms, we show a signature of electron pitch angle scattering driven by Electrostatic Cyclotron Harmonic (ECH) waves in the velocity distribution function (VDF). The diffusion curve of whistler mode waves is used as a proxy to identify changes in VDFs due to wave-particle interactions. We confirm that the shape of the VDF well agrees with the diffusion curve of whistler mode waves when whistler mode chorus alone is active. On the other hand, we find that the shape of the VDF deviates from the diffusion curves at low pitch angles when ECH waves are active following the inactivation of chorus waves. The result is observational support for electron pitch angle scattering caused by ECH waves and suggests that ECH waves can contribute to generation of diffuse auroras. (10.1002/2014GL061927)
  DOI : 10.1002/2014GL061927
• Theory and Modeling for the Magnetospheric Multiscale Mission
  
  • Hesse Michael
  • Aunai Nicolas
  • Birn Joachim
  • Cassak P.
  • Denton R.~e.
  • Drake J. F.
  • Gombosi Tamas I.
  • Hoshino M.
  • Matthaeus W.
  • Sibeck David G.
  • Zenitani Seiji
  Space Science Reviews, Springer Verlag, 2014. The Magnetospheric Multiscale (MMS) mission will provide measurement capabilities, which will exceed those of earlier and even contemporary missions by orders of magnitude. MMS will, for the first time, be able to measure directly and with sufficient resolution key features of the magnetic reconnection process, down to the critical electron scales, which need to be resolved to understand how reconnection works. Owing to the complexity and extremely high spatial resolution required, no prior measurements exist, which could be employed to guide the definition of measurement requirements, and consequently set essential parameters for mission planning and execution. Insight into expected details of the reconnection process could hence only been obtained from theory and modern kinetic modeling. This situation was recognized early on by MMS leadership, which supported the formation of a fully integrated Theory and Modeling Team (TMT). The TMT participated in all aspects of mission planning, from the proposal stage to individual aspects of instrument performance characteristics. It provided and continues to provide to the mission the latest insights regarding the kinetic physics of magnetic reconnection, as well as associated particle acceleration and turbulence, assuring that, to the best of modern knowledge, the mission is prepared to resolve the inner workings of the magnetic reconnection process. The present paper provides a summary of key recent results or reconnection research by TMT members. (10.1007/s11214-014-0078-y)
  DOI : 10.1007/s11214-014-0078-y
• Comment on "Micronewton electromagnetic thruster
  
  • Lafleur Trevor
  Applied Physics Letters, American Institute of Physics, 2014, 105, pp.146101. ... (10.1063/1.4897967)
  DOI : 10.1063/1.4897967
• Numerical simulations used for a validity check on the laser induced photo-detachment diagnostic method in electronegative plasmas
  
  • Oudini N.
  • Taccogna F.
  • Bendib A.
  • Aanesland Ane
  Physics of Plasmas, American Institute of Physics, 2014, 21 (6), pp.063515. Laser photo-detachment is used as a method to measure or determine the negative ion density and temperature in electronegative plasmas. In essence, the method consists of producing an electropositive channel (negative ion free region) via pulsed laser photo-detachment within an electronegative plasma bulk. Electrostatic probes placed in this channel measure the change in the electron density. A second pulse might be used to track the negative ion recovery. From this, the negative ion density and temperature can be determined. We study the formation and relaxation of the electropositive channel via a two-dimensional Particle-In-Cell/Mote Carlo collision model. The simulation is mainly carried out in a Hydrogen plasma with an electronegativity of &#945;&#8201;=&#8201;1, with a parametric study for &#945; up to 20. The temporal and spatial evolution of the plasma potential and the electron densities shows the formation of a double layer (DL) confining the photo-detached electrons within the electropositive channel. This DL evolves into two fronts that move in the opposite directions inside and outside of the laser spot region. As a consequence, within the laser spot region, the background and photo-detached electron energy distribution function relaxes/thermalizes via collisionless effects such as Fermi acceleration and Landau damping. Moreover, the simulations show that collisional effects and the DL electric field strength might play a non-negligible role in the negative ion recovery within the laser spot region, leading to a two-temperature negative ion distribution. The latter result might have important effects in the determination of the negative ion density and temperature from laser photo detachment diagnostic. (10.1063/1.4886144)
  DOI : 10.1063/1.4886144
• Radiation from mixed multi-planar wire arrays
  
  • Safronova Alla S.
  • Kantsyrev Viktor L.
  • Esaulov A. A.
  • Chuvatin Alexandre S.
  • Weller Michael E.
  • Shlyaptseva V. V.
  • Shrestha Ishor
  • Keim S. F.
  • Stafford A.
  • Coverdale C. A.
  • Apruzese J. P.
  • Ouart N. D.
  • Giuliani J. L.
  Physics of Plasmas, American Institute of Physics, 2014, 21 (03), pp.031205. The study of radiation from different wire materials in wire array Z-pinch plasma is a very challenging topic because it is almost impossible to separate different plasmas at the stagnation. A new approach is suggested based on planar wire array (PWA) loads to assess this problem. Multi-planar wire arrays are implemented that consist of few planes, each with the same number of wires and masses but from different wire materials, arranged in parallel rows. In particular, the experimental results obtained with triple PWAs (TPWAs) on the UNR Zebra generator are analyzed with Wire Ablation Dynamics Model, non-local thermodynamic equilibrium kinetic model, and 2D radiation magneto-hydrodynamic to illustrate this new approach. In TPWAs, two wire planes were from mid-atomic-number wire material and another plane was from alloyed Al, placed either in the middle or at the edge of the TPWA. Spatial and temporal properties of K-shell Al and L-shell Cu radiations were analyzed and compared from these two configurations of TPWAs. Advantages of the new approach are demonstrated and future work is discussed. (10.1063/1.4864335)
  DOI : 10.1063/1.4864335
• CLUSTER-STAFF search coil magnetometer calibration - comparisons with FGM
  
  • Robert Patrick
  • Cornilleau-Wehrlin Nicole
  • Piberne Rodrigue
  • de Conchy Y.
  • Lacombe C.
  • Bouzid V.
  • Grison B.
  • Alison Dominique
  • Canu Patrick
  Geoscientific Instrumentation, Methods and Data Systems, European Geosciences Union, 2014, 3, pp.153-177. The main part of the Cluster Spatio-Temporal Analysis of Field Fluctuations (STAFF) experiment consists of triaxial search coils allowing the measurements of the three magnetic components of the waves from 0.1 Hz up to 4 kHz. Two sets of data are produced, one by a module to filter and transmit the corresponding waveform up to either 10 or 180 Hz (STAFF-SC), and the second by the onboard Spectrum Analyser (STAFF-SA) to compute the elements of the spectral matrix for five components of the waves, 3 × B and 2 × E (from the EFW experiment), in the frequency range 8 Hz to 4 kHz. In order to understand the way the output signals of the search coils are calibrated, the transfer functions of the different parts of the instrument are described as well as the way to transform telemetry data into physical units across various coordinate systems from the spinning sensors to a fixed and known frame. The instrument sensitivity is discussed. Cross-calibration inside STAFF (SC and SA) is presented. Results of cross-calibration between the STAFF search coils and the Cluster Fluxgate Magnetometer (FGM) data are discussed. It is shown that these cross-calibrations lead to an agreement between both data sets at low frequency within a 2% error. By means of statistics done over 10 yr, it is shown that the functionalities and characteristics of both instruments have not changed during this period. (10.5194/gi-3-153-2014)
  DOI : 10.5194/gi-3-153-2014
• Acetylene photocatalytic oxidation using continuous flow reactor: Gas phase and adsorbed phase investigation, assessment of the photocatalyst deactivation
  
  • Thevenet F.
  • Guillard C.
  • Rousseau A.
  Chemical Engineering Journal, Elsevier, 2014, 244, pp.50-58. Acetylene, used as a model volatile organic compound (VOC), is submitted to photocatalytic oxidation. This study is based on the simultaneous characterisation of: (i) the gas phase at the reactor outlet; (ii) the adsorbed phase on the photocatalytic media. Experiments are performed in a continuous flow reactor, and analytical procedures have been developed to identify and quantify the gaseous and adsorbed side-products. The photocatalytic media consists in P25 Degussa TiO2 nanoparticles deposited on glass fibres. First, the process efficiency is investigated through C2H2 conversion rate and mineralisation. The treatment performances tend to decrease with time regarding conversion and mineralisation. Then, the oxidation process is investigated through gaseous and adsorbed by-products. Three carboxylic acids have been quantified in the adsorbed phase during oxidative treatment; their temporal evolutions are determined. Their contribution to the carbon balance is discussed. It is evidenced that their adsorption on the photocatalytic media leads to a saturation of the surface. Formaldehyde, glyoxal and formic acid are quantified in the gas phase. Their cumulative temporal profiles and their contribution to the carbon balance confirm the hypothesis of a surface deactivation. The decrease of the process performances with time and the increase of gaseous by-products are correlated with the photocatalyst coverage by adsorbed acids. Carbon balances calculated for various treatment times, give an overview of the process evolution. The regeneration of the photocatalyst surface is possible under synthetic air; 80% of the adsorbed compounds are mineralised. The performances of a cyclic procedure (treatment/regeneration) are evaluated. This approach preserves the photocatalyst performances and ensures a mineralisation of 85% of the converted acetylene. (C) 2014 Elsevier B.V. All rights reserved. (10.1016/j.cej.2014.01.038)
  DOI : 10.1016/j.cej.2014.01.038
• On the relationship between quadrupolar magnetic field and collisionless reconnection
  
  • Smets Roch
  • Aunai Nicolas
  • Belmont Gérard
  • Boniface C.
  • Fuchs J. C.
  Physics of Plasmas, American Institute of Physics, 2014, 21 (6), pp.062111. Using hybrid simulations, we investigate the onset of fast reconnection between two cylindrical magnetic shells initially close to each other. This initial state mimics the plasma structure in High Energy Density Plasmas induced by a laser-target interaction and the associated self-generated magnetic field. We clearly observe that the classical quadrupolar structure of the out-of-plane magnetic field appears prior to the reconnection onset. Furthermore, a parametric study reveals that, with a non-coplanar initial magnetic topology, the reconnection onset is delayed and possibly suppressed. The relation between the out-of-plane magnetic field and the out-of-plane electric field is discussed. (10.1063/1.4885097)
  DOI : 10.1063/1.4885097
• Simulation of long term variation of the F2-layer critical frequency f0F2 at the northern tropical crest of ionization at Phu Thuy, Vietnam with the thermosphere-ionosphere-electrodynamics general circulation model (TIE-GCM)
  
  • Pham Thi Thu Hong
  • Amory-Mazaudier Christine
  • Le Huy Minh
  Vietnam Journal of Earth Sciences, Vietnam Academy of Science and Technology (VAST), 2014 (36), pp.470-479. In this work, the long-term variations of the simulated f0F2 by the NCAR thermosphere ionosphere-electrodynamics general circulation model (TIE-GCM) at the northern tropical crest of ionization at Phu Thuy-Vietnam (geographic latitudes 21.030N and longitude: 105.950E) during the period from 1962 to 2002 are examined to evaluate the ability of this model to reproduce the major features of the f0F2 as observed. The TIE-GCM simulates the influences of migrating and non-migrating diurnal and semidiurnal tides at the lower thermosphere, and changes of geomagnetic activity on the long-term variation of the f0F2. It reproduces well the diurnal and seasonal variations. We analyze the diurnal and seasonal variations of the observed f0F2 at Phu Thuy in approximately the same solar activity condition as in 1964, 1996 for the March and September equinoxes and June and December solstices. The local time and seasonal structures of these simulated results correspond well to those that are observed in 1964. On the contrary, the TIE-GCM model does not reproduce the amplitude observed at Thuy Phu in 1996. The TIE-GCM model with the chosen inputs does not yet allow us to explain well the long-term variations observed at Phu Thuy. We also try the different numerical simulations to understand how the long-term variation of the f0F2 is formed, how it relates to the current global system and its relationship with the thermosphere wind. The simulations show that the calculated NmF2 values are lower than the observed values. We find that the modeled contributions of the migrating and non-migrating diurnal and semidiurnal tides may cause them to play a major role in reducing the amplitude of the NmF2. The contributions of the integrated hemispheric power of auroral electrons and the cross polar cap potential seem to play an important role in increasing the amplitude of the NmF2. Keywords: F2 layer; Long-term trends; Ionosphere equatorial ionization anomaly; Ionosphere (ionospheric conductivities, ionospheric currents and electric field), thermospheric tides, Electrodynamics of the ionosphere (ionospheric dynamo).
• Regeneration of isopropyl alcohol saturated Mn<SUB>X</SUB>O<SUB>Y</SUB> surface: Comparison of thermal, ozonolysis and non-thermal plasma treatments
  
  • Sivachandiran Loganathan
  • Thévenet Frédéric
  • Rousseau Antoine
  Chemical Engineering Journal, Elsevier, 2014, 246, pp.184-195. IPA saturated MnXOY surface regeneration has been investigated under dry air. MnXOY coated glass beads packed-bed reactor has been designed and used for IPA storage under gas-flowing condition at 296 K. The coated MnXOY material is characterized by BrunauerEmmettTeller (BET), non destructive Optical Pro- filometer and X-ray diffraction (XRD) techniques. Atmospheric pressure gas phase Fourier Transform Infrared Spectroscopy (FTIR) and online Thermal Desorption coupled with Gas Phase Chromatography and Mass Spectrometry (TDGCMS) have been respectively used to quantify and to identify the gas phase species produced during the regeneration processes. This study mainly aims at investigating three different methods to regenerate the IPA saturated MnXOY surface. In this framework, methods have been investigated for IPA saturated MnXOY surface regeneration namely (i) direct thermal treatment (DTT), (ii) ozonolysis and (iii) In-Situ Non Thermal Plasma Treatment (NTP). Among the employed methods, In-Situ NTP treatment has shown better regeneration efficiency, and twice more CO2 selectivity. Notably, dry air In-Situ NTP treatment prior to thermal treatment has significantly improved the mineralization. The order of mineralization efficiency and/or COx selectivity can be written as follows: In-Situ NTP > dry air ozonolysis > dry air DTT. (10.1016/j.cej.2014.02.058)
  DOI : 10.1016/j.cej.2014.02.058